e.g. most IT related products are free of duties due to strategic reasons. others have a penalty when imported from countries that do allow/finance price dumping.
If you, as a private person, import goods (shipping) into the EU and it's value is beyond 150€, then you don't have to pay any duties except import-VAT (which is usually the same as the VAT of your country, like 19% in Germany). If you take the goods with you, e.g. back from holiday shopping spree, the minimum is even higher.